Contemporary Kitchen Renovation Surrey

Contemporary Kitchen Renovation Surrey

Accessible home design

Moreover, Canyon Property Projects Ltd emphasizes energy efficiency. Their commitment to exceptional project management means you can relax, knowing your home improvement project is in good hands. In short, Canyon Property Projects Ltd.'s project management excellence means your commercial improvements aren't just completed; they're crafted to meet your highest standards, embodying efficiency, quality, and reliability. Canyon Property Projects Ltd. Learn more about Contemporary Kitchen Renovation Surrey here emphasizes the importance of quality material selection, guiding you through the plethora of options to find what best suits your vision and budget. This foresight prevents costly adjustments down the line, saving you time and money.
Canyon Property Projects Ltd. coordinates everything, keeping you informed with regular updates. They don't just renovate kitchens; they transform them into bespoke spaces that enhance your home's value and your quality of life. You'll be part of a project that values the environment as much as it does craftsmanship. From kitchen and bathroom remodels to full-scale renovations and extensions, they've got you covered.
They'll identify and rectify any imperfections early on, saving you time and money in the long run. Learn more about Canyon Property Projects Ltd. here. This open line ensures that your feedback is heard and acted upon, making you an integral part of the process. Initially, they conduct a detailed inspection to understand the extent of the Poly B piping issue. Porch renovation From upgrading insulation to installing high-efficiency windows and doors, they've got you covered. Read more about Contemporary Kitchen Renovation Surrey here
They understand that your kitchen isn't just a place to cook; it's the heart of your home, where memories are made and shared. Countertop installation Imagine walking into your home and having the lights adjust to your preferred settings, the temperature set just right, and your favorite music playing softly in the background. They prioritize sustainability and efficiency, integrating eco-friendly materials and smart home technologies. From modern kitchen remodels that breathe new life into your home to expansive outdoor living spaces designed for relaxation and entertainment, we've done it all. Structural renovation



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Moreover, they handle everything from initial design to final touches, making the process as seamless as possible. They take your vision and turn it into reality, making sure every aspect of the project reflects your personal style while adding value to your home.

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  11. Garage conversion
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  13. Mudroom design
  14. Home theater installation
  15. Custom cabinetry
  16. Deck and patio remodeling
  17. Interior painting
  18. Kitchen cabinet replacement
  19. Surrey renovation project planning
They're not just builders; they're partners in creating environments that resonate with your personal aesthetic and functional requirements. Their team listens to your vision and translates it into reality, ensuring that every inch of your kitchen is tailored to your preferences and lifestyle.

But it's not just about the materials and systems they install. They're committed to enhancing your home's functionality and efficiency, incorporating the latest technologies and sustainable materials wherever possible. That's why we're committed to not only meeting but exceeding your expectations at every step of the journey.

Whether you're looking to update your kitchen, transform your bathroom, or add an extension, Canyon Property's skilled team has the expertise to deliver exceptional results. Their expertise isn't just about the years they've put in but the depth and breadth of projects they've successfully completed. You'll no longer need to juggle multiple remotes or manually adjust settings throughout your home.

Canyon Property Projects Ltd. adopts a meticulous project management approach, breaking down the entire process into manageable steps. Moreover, Canyon Property Projects Ltd. doesn't just focus on aesthetics. That's the kind of convenience and luxury Canyon Property Projects Ltd. brings to your doorstep.

Citations and other links

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With Canyon Property Projects Ltd., you're not just planning a renovation; you're stepping closer to the home you've always wanted. From the initial consultation to the final walkthrough, you're in capable hands. Just as you're starting to think your home could use a bit of a makeover, it turns out that Canyon Property Projects Ltd., a trusted home improvement contractor in Contemporary Kitchen Renovation Surrey, has expanded their service offerings.

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These success stories are a testament to Canyon Property Projects Ltd's commitment to excellence. Canyon Property Projects Ltd. prioritizes materials that are both sustainable and durable, meaning they'll last longer while reducing waste.

They don't just stop at aesthetics; their services include electrical work, plumbing, and heating solutions, ensuring your home isn't only beautiful but also functional and safe. Their team is well-versed in the latest green technologies, from solar panels to rainwater harvesting systems, making it easier for you to incorporate these into your home if you choose. They use cutting-edge technology to improve your home's energy efficiency, from high-efficiency HVAC systems to LED lighting and eco-friendly insulation. They've embraced materials and methods that minimize environmental impact.

They'll transform your backyard into a personal retreat with features like custom patios, fire pits, and outdoor kitchens, all designed to enhance your home's value and your quality of life.

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After the consultation, you'll receive a detailed proposal outlining the scope of work, timeline, and budget. We've navigated complex renovations, ensuring every detail aligns with our clients' visions and the highest industry standards. They'll work closely with you, ensuring that your ideas aren't just heard, but brought to the forefront of the project.

Instead, they go above and beyond, leveraging their deep industry knowledge and creative problem-solving skills to deliver results that not only meet but exceed your expectations. First impressions count, and your home's curb appeal often determines a visitor's initial perception. Beyond offering comprehensive services, they ensure each project reflects exceptional quality craftsmanship that you'll admire for years. We're well aware that extensive delays can lead to frustration and additional costs.



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Small Bathroom Remodeling Contemporary Kitchen Renovation Surrey
Affordable Home Renovation Contemporary Kitchen Renovation Surrey

Affordable Home Renovation Contemporary Kitchen Renovation Surrey

With Canyon Property Projects Ltd., you're choosing a partner who's proven they can bring any home renovation dream to life. Their team of experienced professionals works closely with you to bring your vision to life, ensuring every detail reflects your personal style and requirements. You can rest easy knowing you've selected a partner who values your satisfaction as much as you do. Fence and gate installation They don't just look at the immediate issue; they consider the long-term implications of their solutions to ensure you won't face similar problems down the line. Accessible home design

This local network they've cultivated doesn't just streamline your project; it embeds a piece of Contemporary Kitchen Renovation Surrey into the very fabric of your home. This means you won't just have a beautiful space but also a practical and reliable one. Ensuring your complete satisfaction is our top priority at Canyon Property Projects Ltd., where we believe in turning your home improvement dreams into reality with precision and care.

They highlight not just the transformative work Canyon Property Projects Ltd. accomplishes but also the values they instill in every project. Canyon Property Projects Ltd. partners with reputable suppliers, ensuring that only the highest quality materials make it into your project. They coordinate with skilled tradespeople, manage supplies, and ensure all work meets the highest standards and compliance with local regulations.

They understand that it's not just about the end result but about providing a smooth, hassle-free experience from start to finish. You're not getting a one-size-fits-all solution; you're getting a home improvement that's as unique as your property and aspirations. Just as you wouldn't attend a professional meeting without ensuring you look presentable, your home should reflect a sense of pride and care. Surrey home renovation company

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With Canyon Property Projects Ltd., you're not just getting a bathroom remodel; you're investing in an experience. Let's create something extraordinary together. Electrical renovations At the heart of their approach, they prioritize offering a service tailored specifically to your unique needs and preferences.

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Whether you're dreaming of a modern kitchen, a luxurious bathroom, or a complete home makeover, they've got the expertise to make it happen.

That's the kind of innovation you'll experience with their designs. They also prioritize sustainability, offering eco-friendly options that can reduce your carbon footprint and save on energy costs in the long run. Moreover, they're committed to using only the highest quality materials, ensuring durability and longevity for your home improvements.

From the initial consultation to the final touches, they prioritize communication, keeping you informed and involved at every step. That's why they're committed to not just meeting, but exceeding your expectations, offering bespoke solutions that turn your vision into reality. Whether you're dreaming of a serene garden to unwind in after a long day, or a vibrant outdoor entertaining area for family and friends, they've got you covered.

Home improvement services

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  • Mudroom design
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  • Custom cabinetry
  • Deck and patio remodeling
  • Interior painting
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  • Landscaping and hardscaping
  • Plumbing upgrades
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What sets Canyon Property Projects Ltd.

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apart isn't just their ability to select the finest materials but also their meticulous attention to detail in every task they undertake. Another family shared their story of expanding their living area, highlighting how Canyon Property Projects Ltd not only met but exceeded their expectations.

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After exploring the exceptional quality and craftsmanship of Canyon Property Projects Ltd, it's essential to highlight how their streamlined process makes your home renovation journey smooth and stress-free.

Home Remodeling Services Contemporary Kitchen Renovation Surrey
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Custom Basement Designs Contemporary Kitchen Renovation Surrey

They understand that the details matter, and they're not about to cut corners. Canyon Property doesn't just offer solutions for these specific plumbing concerns; they excel in a wide range of home improvement services, from simple upgrades to comprehensive renovations. You also need to consider the property's future. They're committed to using only the finest materials, ensuring your bathroom not only looks exquisite but withstands the test of time. You'll find their stories brimming with satisfaction, each detailing how their visions were brought to life with precision and care.

You're not just drafting a plan; you're crafting the roadmap for your dream space. Elevate your home's comfort and sophistication with luxurious bathroom upgrades tailored to your unique style and needs. Hearing directly from satisfied clients underscores the exceptional quality and service provided by Canyon Property Projects Ltd. Improving your home's appeal and functionality can significantly increase its market value.

Opting for a bold color or a unique design can add character and charm, enticing potential buyers or simply making your home the envy of the neighborhood. This means your home improvement isn't just a personal upgrade but a smart, local market-aligned investment. This means minimizing waste by recycling materials whenever possible and choosing locally sourced products to reduce transportation emissions. Canyon Property Projects Ltd. offers a wide array of home improvement services, ensuring you'll find exactly what you need for your project. Surrey custom home upgrades

From initial sketches to final touches, they ensure the end result isn't just a house, but a home that resonates with your identity. Whatever your dream, understanding these requirements clearly is crucial. If you're a realtor, think about the potential buyers or renters. This includes the project phases, materials needed, and cost estimates, ensuring transparency from the start.

Home Renovation Contemporary Kitchen Renovation Surrey

This is crucial because nothing slows down a project like red tape. Their team dives deep into the specifics of what you're looking for, ensuring every detail from cabinetry to countertops embodies your unique vision. Whether you're dreaming of a modern minimalist kitchen with sleek finishes or a cozy, traditional space with warm wood tones, they've got the expertise to bring it to life. With Canyon Property Projects Ltd, you're not just getting a contractor; you're partnering with a team that's invested in bringing your vision to life with precision, creativity, and care.
This means you get the highest standard of work across all aspects of your project, be it plumbing, electrical, or interior design. Whether you're dreaming of a modern, open-plan kitchen or a luxurious, spa-like bathroom, they've got the expertise to make it happen. You're not just hiring a company; you're partnering with a team dedicated to bringing your vision to life.
From the initial consultation to the final walkthrough, you're in capable hands.

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  • Financing options for renovation
  • Baseboard and trim renovation
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The quality of work and the speed of execution were outstanding. If you're aiming to reduce your carbon footprint or incorporate smart home features, Canyon Property Projects Ltd. is ready to bring those visions to life.
Imagine your drab kitchen, with its worn-out countertops and old cabinets, transformed into a sleek, functional space where you love to spend time. Laundry room renovation You'll work closely with their team to define your vision, set clear goals, and establish a timeline that suits your schedule. It's like watching your property come back to life, rejuvenated and ready to stand out in Contemporary Kitchen Renovation Surrey's competitive real estate market.

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Home Renovation Contemporary Kitchen Renovation Surrey
Polybutylene
Names
Other names
polybutene-1, poly(1-butene), PB-1
Identifiers
ChemSpider
  • none
ECHA InfoCard 100.111.056 Edit this at Wikidata
Properties
(C4H8)n
Density 0.95 g/cm3[1]
Melting point 135 °C (275 °F; 408 K)[1]
Related compounds
Related compounds
1-butene (monomer)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Polybutylene (polybutene-1, poly(1-butene), PB-1) is a polyolefin or saturated polymer with the chemical formula (CH2CH(Et))n. Not be confused with polybutene, PB-1 is mainly used in piping.[2]

Production

[edit]

Polybutylene is produced by polymerisation of 1-butene using supported Ziegler–Natta catalysts.

Catalysts

[edit]

Isotactic PB-1 is produced commercially using two types of heterogeneous Ziegler–Natta catalysts.[3] The first type of catalyst contains two components, a solid pre-catalyst, the δ-crystalline form of TiCl3, and solution of an organoaluminum cocatalyst, such as Al(C2H5)3. The second type of pre-catalyst is supported. The active ingredient in the catalyst is TiCl4 and the support is microcrystalline MgCl2. These catalysts also contain special modifiers, organic compounds belonging to the classes of esters or ethers. The pre-catalysts are activated by combinations of organoaluminum compounds and other types of organic or organometallic modifiers. Two most important technological advantages of the supported catalysts are high productivity and a high fraction of the crystalline isotactic polymer they produce at 70–80 °C under standard polymerization conditions.[4][5][6]

Characteristics

[edit]

PB-1 is a high molecular weight, linear, isotactic, and semi-crystalline polymer. PB-1 combines typical characteristics of conventional polyolefins with certain properties of technical polymers.

PB-1, when applied as a pure or reinforced resin, can replace materials like metal, rubber and engineering polymers. It is also used synergistically as a blend element to modify the characteristics of other polyolefins like polypropylene and polyethylene. Because of its specific properties it is mainly used in pressure piping, flexible packaging, water heaters, compounding and hot melt adhesives.

Heated up to 190 °C and above, PB-1 can easily be compression moulded, injection moulded, blown to hollow parts, extruded, and welded. It does not tend to crack due to stress.[dubiousdiscuss] Because of its crystalline structure and high molecular weight, PB-1 has good resistance to hydrostatic pressure, showing very low creep even at elevated temperatures.[7] It is flexible, resists impact well and has good elastic recovery.[3][8]

Isotactic polybutylene crystallizes in three different forms. Crystallization from solution yields form-III with the melting point of 106.5 °C. Cooling from the melt results in the form II which has melting point of 124 °C and density of 0.89 g/cm3. At room temperature, it spontaneously converts into the form-I with the melting point of 135 °C and density of 0.95 g/cm3.[1]

PB-1 generally resists chemicals such as detergents, oils, fats, acids, bases, alcohol, ketones, aliphatic hydrocarbons and hot polar solutions (including water).[3] It shows lower resistance to aromatic and chlorinated hydrocarbons as well as oxidising acids than other polymers such as polysulfone and polyamide 6/6.[7] Additional features include excellent wet abrasion resistance, easy melt flowability (shear thinning), and good dispersion of fillers. It is compatible with polypropylene, ethylene propylene rubbers, and thermoplastic elastomers.

Some properties:[7]

Application areas

[edit]

Piping systems

[edit]

The main use of PB-1 is in flexible pressure piping systems for hot and cold drinking water distribution, pre-insulated district heating networks and surface heating and cooling systems. ISO 15876 defines the performance requirements of PB-1 piping systems.[9] PB-1's most notable characteristics are weldability, temperature resistance, flexibility and high hydrostatic pressure resistance. The material can be classified PB 125 with a minimum required strength (MRS) of 12.5 MPa. Other features include low noise transmission, low linear thermal expansion, no corrosion and calcification.

PB-1 piping systems are no longer being sold in North America (see "Class action lawsuits and removal from building code approved usage", below). The overall market share in Europe and Asia is rather small but PB-1 piping systems have shown a steady growth in recent years. In certain domestic markets, e.g. Kuwait, the United Kingdom, Korea and Spain, PB-1 piping systems have a strong position.[8]

Plastic packaging

[edit]

Several PB-1 grades are commercially available for various applications and conversion technologies (blown film, cast film, extrusion coating). There are two main fields of application:

  • Peelable easy-to-open packaging where PB-1 is used as blend component predominantly in polyethylene to tailor peel strength and peel quality, mainly in alimentary consumer packaging and medical packaging.
  • Lowering seal initiation temperature (SIT) of high speed packaging polypropylene based films. Blending PB-1 into polypropylene, heat sealing temperatures as low as 65 °C can be achieved, maintaining a broad sealing window and good optical film properties.

Hot melt adhesives

[edit]

PB-1 is compatible with a wide range of tackifier resins. It offers high cohesive and adhesive strength and helps tailoring the "open time" of the adhesive (up to 30 minutes) because of its slow crystallisation kinetics. It improves the thermal stability and the viscosity of the adhesive.[10]

Compounding and masterbatches

[edit]

PB-1 accepts very high filler loadings in excess of 70%. In combination with its low melting point it can be employed in halogen-free flame retardant composites or as masterbatch carrier for thermo-sensitive pigments. PB-1 disperses easily in other polyolefins, and at low concentration, acts as processing aid reducing torque and/or increasing throughput.

Thermal insulation

[edit]

PB-1 can be foamed.[11] The use of PB-1 foam as thermal insulation is of great advantage for district heating pipes, since the number of materials in the sandwich structure is reduced to one, facilitating its recycling.[12]

Other applications

[edit]

Other applications include domestic water heaters, electrical insulation, compression packaging, wire and cable, shoe soles, and polyolefin modification (thermal bonding, enhancing softness and flexibility of rigid compounds, increasing temperature resistance and compression set of soft compounds).

Environmental longevity

[edit]

Plumbing and heating systems made from PB-1 have been used in Europe and Asia for more than 30 years. First reference projects in district heating and floor heating systems in Germany and Austria from the early 1970s are still in operation today.[8]

One example is the installation of PB-1 pipes in the Vienna Geothermal Project (1974) where aggressive geothermal water is distributed at a service temperature of 54 °C and 10 bar pressure. Other pipe materials in the same installation failed or corroded and had been replaced in the meantime.[8]

International standards set minimum performance requirements for pipes made from PB-1 used in hot water applications. Standardized extrapolation methods predict lifetimes in excess of 50 years at 70 °C and 10 bar.[8]

Class action lawsuits and removal from building code approved usage

[edit]

Polybutylene plumbing was used in several million homes built in the United States from around 1978 to 1997. Problems with leaks and broken pipes led to a class action lawsuit, Cox v. Shell Oil, that was settled for $1 billion.[13][14] The leaks were associated with degradation of polybutylene exposed to chlorinated water.[15]

Polybutylene water pipes are no longer accepted by the United States building codes and have been the subject[16] of class action lawsuits in both Canada and the U.S.[17][18] The National Plumbing Code of Canada 1995 listed polybutylene piping as acceptable for use with the exception of recirculation plumbing. The piping was removed from the acceptable for use list in the 2005 issue of the standard.[19]

In Australia in March 2023, the Department of Mines, Industry Regulation and Safety reported that Australian homes built in 2019-2020 that had used a certain brand of polybutylene piping, had become the subject of an enquiry due to the significance of water leaks reported.[20][21]

There is evidence to suggest that the presence of chlorine and chloramine compounds in municipal water (often deliberately added to retard bacterial growth) will cause deterioration of the internal chemical structure of polybutylene piping and the associated acetal fittings.[22] The reaction with chlorinated water appears to be greatly accelerated by tensile stress, and is most often observed in material under highest mechanical stress such as at fittings, sharp bends, and kinks. Localized stress whitening of the material generally accompanies and precedes decomposition of the polymer. In extreme cases, this stress-activated chemical "corrosion" can lead to perforation and leakage within a few years, but it also may not fail for decades. Fittings with a soft compression seal can give adequate service life.[further explanation needed]

Because the chemical reaction of the water with the pipe occurs inside the pipe, it is often difficult to assess the extent of deterioration. The problem can cause both slow leaks and pipe bursting without any previous warning indication. The only long-term solution is to completely replace the polybutylene plumbing throughout the entire building.[23]

See also

[edit]

References

[edit]
  1. ^ a b c Mark Alger, Mark S. M. Alger (1997). Polymer science dictionary. Springer. p. 398. ISBN 978-0-412-60870-4.
  2. ^ Whiteley, Kenneth S.; Heggs, T. Geoffrey; Koch, Hartmut; Mawer, Ralph L.; Immel, Wolfgang (2000). "Polyolefins". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a21_487. ISBN 978-3527306732.
  3. ^ a b c d Charles A. Harper (2006). Handbook of plastics technologies: the complete guide to properties and performance. McGraw-Hill Professional. p. 17. ISBN 978-0-07-146068-2.
  4. ^ Hwo, Charles C.; Watkins, Larry K. Laminated film with improved tear strength, European Patent Application EP0459742, Publication date 12/04/1991
  5. ^ Boo-Deuk Kim et al. (2008) U.S. patent 7,442,489
  6. ^ Shimizu, Akihiko; Itakura, Keisuke; Otsu, Takayuki; Imoto, Minoru (1969). "Monomer-isomerization polymerization. VI. Isomerizations of butene-2 with TiCl3 or Al(C2H5)3–TiCl3 catalyst". Journal of Polymer Science Part A: Polymer Chemistry. 7 (11): 3119. Bibcode:1969JPoSA...7.3119S. doi:10.1002/pol.1969.150071108.
  7. ^ a b c d Freeman, Andrew; Mantell, Susan C.; Davidson, Jane H. (2005). "Mechanical performance of polysulfone, polybutylene, and polyamide 6/6 in hot chlorinated water". Solar Energy. 79 (6): 624–37. Bibcode:2005SoEn...79..624F. doi:10.1016/j.solener.2005.07.003.
  8. ^ a b c d e Polybutylene Archived November 30, 2006, at the Wayback Machine
  9. ^ ISO 15876-1:2003 iso.org
  10. ^ T.E. Rolando (1998). Solvent-Free Adhesives. iSmithers Rapra. p. 35. ISBN 978-1-85957-133-0.
  11. ^ Doyle, Lucía (2022-03-20). "Extrusion foaming behavior of polybutene-1. Toward single-material multifunctional sandwich structures". Journal of Applied Polymer Science. 139 (12). doi:10.1002/app.51816. ISSN 0021-8995.
  12. ^ Doyle Gutierrez, Lucia (2022-12-02). A Circular Economy Approach to Multifunctional Sandwich Structures: Polymeric Foams for District Heating Pre-Insulated Pipes (Thesis thesis). HafenCity Universität Hamburg. doi:10.34712/142.35.
  13. ^ Hensler, Deborah R.; Pace, Nicholas M.; Dombey-Moore, Bonita; Giddens, Beth; Gross, Jennifer; Moller, Erik K. (2000). "Polybutylene Plumbing Pipes Litigation: Cox v. Shell Oil". In Hensler, Deborah R. (ed.). Class action dilemmas: pursuing public goals for private gain. Santa Monica, CA: RAND Institute for Civil Justice. pp. 375–98. ISBN 978-0-8330-2601-9.
  14. ^ Schneider, Martin (November 21, 1999). "Pipe problem getting fixed". The Baltimore Sun. Archived from the original on 2012-06-04. Retrieved 2010-07-29.
  15. ^ Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Assessing material performance in chlorinated potable water applications" (PDF). Book Institute of Materials. 759: 863–72. ISSN 1366-5510. Archived from the original (PDF) on 2010-06-22. Retrieved 2010-07-30. also published as: Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Chlorine resistance testing of cross-linked polyethylene piping materials". ANTEC 2001 Proceedings. Boca Raton: CRC Press. pp. 2833–9. ISBN 978-1-58716-098-1.
  16. ^ Pipe dream is nightmare for many, Miami Herald - September 12, 1993
  17. ^ "DuPont USA Settlement of the Canadian Class Action Lawsuits". Archived from the original on 2011-07-06. Retrieved 2010-10-01.
  18. ^ Polybutylene Plumbing Pipe Leak Relief
  19. ^ "Polybutylene (Poly-B) Pressure Water Piping" (PDF). municipalaffairs.alberta.ca. Government of Alberta. 2012-01-06. Retrieved 2019-09-09.
  20. ^ "Information for owners of new homes with polybutylene plumbing pipes" (PDF). commerce.wa.gov.au. March 21, 2023. Archived (PDF) from the original on 12 November 2023. Retrieved November 12, 2023.
  21. ^ Batajtis, Damian (27 March 2023). "Comprehensive Guide to polybutylene Piping Issues and Solutions in Australia". Wizard Leak Detection. Archived from the original on 12 November 2023. Retrieved November 12, 2023.
  22. ^ Cause of failure in polybutylene pipe & acetal fittings http://www.polybutylene.com/poly.html
  23. ^ "Polybutylene Piping". PropEx.com. Archived from the original on 2015-08-29. Retrieved 2015-07-17.

Further reading

[edit]

Polybutylene
Names
Other names
polybutene-1, poly(1-butene), PB-1
Identifiers
ChemSpider
  • none
ECHA InfoCard 100.111.056 Edit this at Wikidata
Properties
(C4H8)n
Density 0.95 g/cm3[1]
Melting point 135 °C (275 °F; 408 K)[1]
Related compounds
Related compounds
1-butene (monomer)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Polybutylene (polybutene-1, poly(1-butene), PB-1) is a polyolefin or saturated polymer with the chemical formula (CH2CH(Et))n. Not be confused with polybutene, PB-1 is mainly used in piping.[2]

Production

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Polybutylene is produced by polymerisation of 1-butene using supported Ziegler–Natta catalysts.

Catalysts

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Isotactic PB-1 is produced commercially using two types of heterogeneous Ziegler–Natta catalysts.[3] The first type of catalyst contains two components, a solid pre-catalyst, the δ-crystalline form of TiCl3, and solution of an organoaluminum cocatalyst, such as Al(C2H5)3. The second type of pre-catalyst is supported. The active ingredient in the catalyst is TiCl4 and the support is microcrystalline MgCl2. These catalysts also contain special modifiers, organic compounds belonging to the classes of esters or ethers. The pre-catalysts are activated by combinations of organoaluminum compounds and other types of organic or organometallic modifiers. Two most important technological advantages of the supported catalysts are high productivity and a high fraction of the crystalline isotactic polymer they produce at 70–80 °C under standard polymerization conditions.[4][5][6]

Characteristics

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PB-1 is a high molecular weight, linear, isotactic, and semi-crystalline polymer. PB-1 combines typical characteristics of conventional polyolefins with certain properties of technical polymers.

PB-1, when applied as a pure or reinforced resin, can replace materials like metal, rubber and engineering polymers. It is also used synergistically as a blend element to modify the characteristics of other polyolefins like polypropylene and polyethylene. Because of its specific properties it is mainly used in pressure piping, flexible packaging, water heaters, compounding and hot melt adhesives.

Heated up to 190 °C and above, PB-1 can easily be compression moulded, injection moulded, blown to hollow parts, extruded, and welded. It does not tend to crack due to stress.[dubiousdiscuss] Because of its crystalline structure and high molecular weight, PB-1 has good resistance to hydrostatic pressure, showing very low creep even at elevated temperatures.[7] It is flexible, resists impact well and has good elastic recovery.[3][8]

Isotactic polybutylene crystallizes in three different forms. Crystallization from solution yields form-III with the melting point of 106.5 °C. Cooling from the melt results in the form II which has melting point of 124 °C and density of 0.89 g/cm3. At room temperature, it spontaneously converts into the form-I with the melting point of 135 °C and density of 0.95 g/cm3.[1]

PB-1 generally resists chemicals such as detergents, oils, fats, acids, bases, alcohol, ketones, aliphatic hydrocarbons and hot polar solutions (including water).[3] It shows lower resistance to aromatic and chlorinated hydrocarbons as well as oxidising acids than other polymers such as polysulfone and polyamide 6/6.[7] Additional features include excellent wet abrasion resistance, easy melt flowability (shear thinning), and good dispersion of fillers. It is compatible with polypropylene, ethylene propylene rubbers, and thermoplastic elastomers.

Some properties:[7]

Application areas

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Piping systems

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The main use of PB-1 is in flexible pressure piping systems for hot and cold drinking water distribution, pre-insulated district heating networks and surface heating and cooling systems. ISO 15876 defines the performance requirements of PB-1 piping systems.[9] PB-1's most notable characteristics are weldability, temperature resistance, flexibility and high hydrostatic pressure resistance. The material can be classified PB 125 with a minimum required strength (MRS) of 12.5 MPa. Other features include low noise transmission, low linear thermal expansion, no corrosion and calcification.

PB-1 piping systems are no longer being sold in North America (see "Class action lawsuits and removal from building code approved usage", below). The overall market share in Europe and Asia is rather small but PB-1 piping systems have shown a steady growth in recent years. In certain domestic markets, e.g. Kuwait, the United Kingdom, Korea and Spain, PB-1 piping systems have a strong position.[8]

Plastic packaging

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Several PB-1 grades are commercially available for various applications and conversion technologies (blown film, cast film, extrusion coating). There are two main fields of application:

  • Peelable easy-to-open packaging where PB-1 is used as blend component predominantly in polyethylene to tailor peel strength and peel quality, mainly in alimentary consumer packaging and medical packaging.
  • Lowering seal initiation temperature (SIT) of high speed packaging polypropylene based films. Blending PB-1 into polypropylene, heat sealing temperatures as low as 65 °C can be achieved, maintaining a broad sealing window and good optical film properties.

Hot melt adhesives

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PB-1 is compatible with a wide range of tackifier resins. It offers high cohesive and adhesive strength and helps tailoring the "open time" of the adhesive (up to 30 minutes) because of its slow crystallisation kinetics. It improves the thermal stability and the viscosity of the adhesive.[10]

Compounding and masterbatches

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PB-1 accepts very high filler loadings in excess of 70%. In combination with its low melting point it can be employed in halogen-free flame retardant composites or as masterbatch carrier for thermo-sensitive pigments. PB-1 disperses easily in other polyolefins, and at low concentration, acts as processing aid reducing torque and/or increasing throughput.

Thermal insulation

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PB-1 can be foamed.[11] The use of PB-1 foam as thermal insulation is of great advantage for district heating pipes, since the number of materials in the sandwich structure is reduced to one, facilitating its recycling.[12]

Other applications

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Other applications include domestic water heaters, electrical insulation, compression packaging, wire and cable, shoe soles, and polyolefin modification (thermal bonding, enhancing softness and flexibility of rigid compounds, increasing temperature resistance and compression set of soft compounds).

Environmental longevity

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Plumbing and heating systems made from PB-1 have been used in Europe and Asia for more than 30 years. First reference projects in district heating and floor heating systems in Germany and Austria from the early 1970s are still in operation today.[8]

One example is the installation of PB-1 pipes in the Vienna Geothermal Project (1974) where aggressive geothermal water is distributed at a service temperature of 54 °C and 10 bar pressure. Other pipe materials in the same installation failed or corroded and had been replaced in the meantime.[8]

International standards set minimum performance requirements for pipes made from PB-1 used in hot water applications. Standardized extrapolation methods predict lifetimes in excess of 50 years at 70 °C and 10 bar.[8]

Class action lawsuits and removal from building code approved usage

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Polybutylene plumbing was used in several million homes built in the United States from around 1978 to 1997. Problems with leaks and broken pipes led to a class action lawsuit, Cox v. Shell Oil, that was settled for $1 billion.[13][14] The leaks were associated with degradation of polybutylene exposed to chlorinated water.[15]

Polybutylene water pipes are no longer accepted by the United States building codes and have been the subject[16] of class action lawsuits in both Canada and the U.S.[17][18] The National Plumbing Code of Canada 1995 listed polybutylene piping as acceptable for use with the exception of recirculation plumbing. The piping was removed from the acceptable for use list in the 2005 issue of the standard.[19]

In Australia in March 2023, the Department of Mines, Industry Regulation and Safety reported that Australian homes built in 2019-2020 that had used a certain brand of polybutylene piping, had become the subject of an enquiry due to the significance of water leaks reported.[20][21]

There is evidence to suggest that the presence of chlorine and chloramine compounds in municipal water (often deliberately added to retard bacterial growth) will cause deterioration of the internal chemical structure of polybutylene piping and the associated acetal fittings.[22] The reaction with chlorinated water appears to be greatly accelerated by tensile stress, and is most often observed in material under highest mechanical stress such as at fittings, sharp bends, and kinks. Localized stress whitening of the material generally accompanies and precedes decomposition of the polymer. In extreme cases, this stress-activated chemical "corrosion" can lead to perforation and leakage within a few years, but it also may not fail for decades. Fittings with a soft compression seal can give adequate service life.[further explanation needed]

Because the chemical reaction of the water with the pipe occurs inside the pipe, it is often difficult to assess the extent of deterioration. The problem can cause both slow leaks and pipe bursting without any previous warning indication. The only long-term solution is to completely replace the polybutylene plumbing throughout the entire building.[23]

See also

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References

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  1. ^ a b c Mark Alger, Mark S. M. Alger (1997). Polymer science dictionary. Springer. p. 398. ISBN 978-0-412-60870-4.
  2. ^ Whiteley, Kenneth S.; Heggs, T. Geoffrey; Koch, Hartmut; Mawer, Ralph L.; Immel, Wolfgang (2000). "Polyolefins". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a21_487. ISBN 978-3527306732.
  3. ^ a b c d Charles A. Harper (2006). Handbook of plastics technologies: the complete guide to properties and performance. McGraw-Hill Professional. p. 17. ISBN 978-0-07-146068-2.
  4. ^ Hwo, Charles C.; Watkins, Larry K. Laminated film with improved tear strength, European Patent Application EP0459742, Publication date 12/04/1991
  5. ^ Boo-Deuk Kim et al. (2008) U.S. patent 7,442,489
  6. ^ Shimizu, Akihiko; Itakura, Keisuke; Otsu, Takayuki; Imoto, Minoru (1969). "Monomer-isomerization polymerization. VI. Isomerizations of butene-2 with TiCl3 or Al(C2H5)3–TiCl3 catalyst". Journal of Polymer Science Part A: Polymer Chemistry. 7 (11): 3119. Bibcode:1969JPoSA...7.3119S. doi:10.1002/pol.1969.150071108.
  7. ^ a b c d Freeman, Andrew; Mantell, Susan C.; Davidson, Jane H. (2005). "Mechanical performance of polysulfone, polybutylene, and polyamide 6/6 in hot chlorinated water". Solar Energy. 79 (6): 624–37. Bibcode:2005SoEn...79..624F. doi:10.1016/j.solener.2005.07.003.
  8. ^ a b c d e Polybutylene Archived November 30, 2006, at the Wayback Machine
  9. ^ ISO 15876-1:2003 iso.org
  10. ^ T.E. Rolando (1998). Solvent-Free Adhesives. iSmithers Rapra. p. 35. ISBN 978-1-85957-133-0.
  11. ^ Doyle, Lucía (2022-03-20). "Extrusion foaming behavior of polybutene-1. Toward single-material multifunctional sandwich structures". Journal of Applied Polymer Science. 139 (12). doi:10.1002/app.51816. ISSN 0021-8995.
  12. ^ Doyle Gutierrez, Lucia (2022-12-02). A Circular Economy Approach to Multifunctional Sandwich Structures: Polymeric Foams for District Heating Pre-Insulated Pipes (Thesis thesis). HafenCity Universität Hamburg. doi:10.34712/142.35.
  13. ^ Hensler, Deborah R.; Pace, Nicholas M.; Dombey-Moore, Bonita; Giddens, Beth; Gross, Jennifer; Moller, Erik K. (2000). "Polybutylene Plumbing Pipes Litigation: Cox v. Shell Oil". In Hensler, Deborah R. (ed.). Class action dilemmas: pursuing public goals for private gain. Santa Monica, CA: RAND Institute for Civil Justice. pp. 375–98. ISBN 978-0-8330-2601-9.
  14. ^ Schneider, Martin (November 21, 1999). "Pipe problem getting fixed". The Baltimore Sun. Archived from the original on 2012-06-04. Retrieved 2010-07-29.
  15. ^ Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Assessing material performance in chlorinated potable water applications" (PDF). Book Institute of Materials. 759: 863–72. ISSN 1366-5510. Archived from the original (PDF) on 2010-06-22. Retrieved 2010-07-30. also published as: Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Chlorine resistance testing of cross-linked polyethylene piping materials". ANTEC 2001 Proceedings. Boca Raton: CRC Press. pp. 2833–9. ISBN 978-1-58716-098-1.
  16. ^ Pipe dream is nightmare for many, Miami Herald - September 12, 1993
  17. ^ "DuPont USA Settlement of the Canadian Class Action Lawsuits". Archived from the original on 2011-07-06. Retrieved 2010-10-01.
  18. ^ Polybutylene Plumbing Pipe Leak Relief
  19. ^ "Polybutylene (Poly-B) Pressure Water Piping" (PDF). municipalaffairs.alberta.ca. Government of Alberta. 2012-01-06. Retrieved 2019-09-09.
  20. ^ "Information for owners of new homes with polybutylene plumbing pipes" (PDF). commerce.wa.gov.au. March 21, 2023. Archived (PDF) from the original on 12 November 2023. Retrieved November 12, 2023.
  21. ^ Batajtis, Damian (27 March 2023). "Comprehensive Guide to polybutylene Piping Issues and Solutions in Australia". Wizard Leak Detection. Archived from the original on 12 November 2023. Retrieved November 12, 2023.
  22. ^ Cause of failure in polybutylene pipe & acetal fittings http://www.polybutylene.com/poly.html
  23. ^ "Polybutylene Piping". PropEx.com. Archived from the original on 2015-08-29. Retrieved 2015-07-17.

Further reading

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